My best guess is to make sure the bleeder on the passenger rear wheel cylinder is open while the other 3 are closed.
Get one of those really big bottles of brakes fluid and flip it upside down in the master cylinder so the nose of it in under the upper ridge of the master cylinder. Best to not open up the foil seal all the way on the bottle but rather pop 2 holes with a screw driver to be able to control the flow of fluid better when the time comes to remove the bottle.
Gravity bleed or pump the master with only the pass. rear wheel cyinder open until there are no air bubbles. Close the bleeder then bleed the driver's rear, then passenger caliper, then the driver's caliper.
Always keep an eye on the level in the master so you don't suck in air.
I don't know about DOT 3 vs synthetic but unless you do some crazy driving the DOT 3 shouldn't boil over.