I'd prefer to de arch the spring. Lowering blocks must be machined with an angle in them, as they will change the pinion angle and possibly create a vibration.
Just about every Mopar I've seen has the rear slightly offset. Some more than others.
As far as the alignment is concerned, it needs to be put on the machine, and all the starting measurements need to be taken. Then, you figure a game plan. It took me 3-4 hours at night on a friends machine to heights, level, shim, adj strut rods, re check and do cast/camb/toe.