The front brakes should be going to the LARGER of the 2 resevoirs on the mAster cylinder. You can confirm this by bleeding the front brakes and seeing which one lowers in fluid. The larger one of the 2, should not have a RP valve in it.
If you drive the car, then immediately jack up the wheel, can you spin it by hand? There should only be a slight drag and not feel like the brakes are stuck. If they feel too tight, turn the wheel to the outside and reach in there with a wrench to open the bleeder screw to see if any pressure releases. If it does and releases the brake, it could be a bad booster. Try it with the engine running too.
You need to find out if pressure is coming from the hydraulic side or if it is mechanically binding at the caliper.
Rob