there are 6 pistons spaced evenly at 120* apart so yes 2 pistons are at TDC at the same time , 1 is firing the other is at the top of exhaust stroke , the heads are offset slightly the one that is 1/2" closer to the front of the engine will be # 1 , not sure on the firing order but if the wires are still on the cap all you need is the wire to #1 plug , pull the plug & bump the engine over until you feel compression on #1 cylinder & point the rotor to that wire on the cap
I hope this helps