1- Yes , Teflon pipe sealer or silicone will work .
2- spacers can be helpful for limiting heat to the carb , 1/2 " or so be careful of hood clearance , I would also recommend blocking the heat crossover in the manifold using a piece of the old gasket cut to fit .
3- Do not use stainless bolts , they will often tear up the threads , gall etc , you need use regular steel bolts .
4- Ultra Grey or Black silicone if the gaskets do not have sealer already on them , use along the bottom of the gaskets where the oil will try to seep up , & around the water ports also use some silicone on the bolts so oil will not come up the bolt threads .